The enolization of ketonic substrates is a cornerstone reaction in modern organic synthesis. The research in this book is split into three main sections, with the investigation of s-block metal enolate chemistry being the underlying theme: The first section focuses on the synthesis and characterization of a series of homo- and heterobimetallic potassium and calcium enolates. The second section concentrates on an investigation into the utility of Ca(HMDS)2 to mediate the enolization of ketonic substrates. The final section outlines a detailed mechanistic study for the enolization of propiophenone mediated by Mg(HMDS)2 in toluene.
| Autorius: | Xuyang He |
| Leidėjas: | LAP LAMBERT Academic Publishing |
| Išleidimo metai: | 2009 |
| Knygos puslapių skaičius: | 220 |
| ISBN-10: | 3838300165 |
| ISBN-13: | 9783838300160 |
| Formatas: | Knyga minkštu viršeliu |
| Kalba: | Anglų |
| Žanras: | Chemistry |
Parašykite atsiliepimą apie „ENOLIZATION REACTIONS MEDIATED BY S-BLOCK METAL AMIDE REAGENTS: Performance of Alkali and Alkaline Earth Metal Amides in Enolization of Ketones and the Mechanism behind E-stereoselectivity in non-polar solvents“
