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Free Energy Relationships in Organic and Bio-Organic Chemistry

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Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.

Informacija

Autorius: Andrew Williams
Leidėjas: Royal Society of Chemistry
Išleidimo metai: 2003
Knygos puslapių skaičius: 290
ISBN-13: 9780854046768
Formatas: 6.14 x 0.66 x 9.21258 inches. Knyga minkštu viršeliu
Kalba: Anglų

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